Vinogradov Alexander A., Komarov Pavel D., Puntus Lada N., Taydakov Ilya V., Lyssenko Konstantin A., Nifant'ev Ilya E., Varaksina Evgenia A., Roitershtein Dmitrii M. Luminescence sensitization of the Nd3+ ion in diphenyl(9-antnracenyl)cyclopentadienyl complexes containing antenna-ligand with extended π-system. Inorganica Chimica Acta , 2022 , 533. р. 120777. ISSN 00201693
Полный текст не доступен из этого репозитория.Аннотация
Mono-3,4-diphenyl(9-anthracenyl)cyclopentadienyl dichloride complexes {[CpAntLn(thf)]2(µ2-Cl)2(µ3-Cl)3K(thf)}2 Ln= Nd, Gd, Tb, CpAnt = Ph2(C14H9)C5H2 were synthesized and structurally characterized. All the complexes were obtained in the form of tetranuclear ate complexes consisting of two [CpAntLn(thf)]2(µ2-Cl)2(µ3-Cl)3K(thf) units connected via two K−Cl bonds. In the Tb complex, anthracene fragments from two different molecules participate in the stacking interactions with a high degree of π-system overlap. Characteristic luminescence of the Nd³⁺ ion was obtained for the first time for the Nd-cyclopentadienyl complex. Energies of singlet and triplet states for CpAnt ligand were estimated.
| Тип объекта: | Статья |
|---|---|
| Авторы на русском. ОБЯЗАТЕЛЬНО ДЛЯ АНГЛОЯЗЫЧНЫХ ПУБЛИКАЦИЙ!: | A.A. Виноградов, П.Д. Комаров, Л.Н. Пунтус, И.В. Тайдаков, К.A. Лыссенко, И.Е. Нифантъев, Е.A. Вараксина, Д.М. Роитерштейн |
| Подразделения (можно выбрать несколько, удерживая Ctrl): | 215 лаб. проблем субмикронной технологии |
| URI: | http://cplire.ru:8080/id/eprint/9091 |
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