Kalugin Alexey E., Lyssenko Konstantin A., Minyaev Mikhail E., Roitershtein Dmitrii M., Puntus Lada N., Varaksina Evgenia A., Nifant'ev Ilya E. Crystal structure of tris[bis(2,6-diisopropylphenyl) phosphato-κO]pentakis(methanol-κO)europium methanol monosolvate. Acta Crystallographica Section E Crystallographic Communications , 2019 , 75 (12). С. 1892-1896. ISSN 2056-9890
Полный текст не доступен из этого репозитория.Аннотация
The mononuclear title complex, [Eu(C24H34O4P)3(CH4O)5]·CH4O, (1), has been obtained as a minor product in the reaction between EuCl3(H2O)6 and lithium bis¬(2,6-diiso¬propyl-phen¬yl) phosphate in a 1:3 molar ratio in a methanol medium. Its structure exhibits monoclinic (P21/c) symmetry at 120 K and is isostructural with the La, Ce and Nd analogs reported previously [Minyaev et al. (2018a). Acta Cryst. C74, 590–598]. In (1), all three bis¬(2,6-diiso¬propyl¬phen¬yl) phosphate ligands display the terminal κ1O-coordination mode. All of the hy¬droxy H atoms are involved in O—H O hydrogen bonding, exhibiting four intra¬molecular and two inter¬molecular hydrogen bonds. Photophysical studies have demonstrated luminescence of (1) with a low quantum yield.
| Тип объекта: | Статья |
|---|---|
| Авторы на русском. ОБЯЗАТЕЛЬНО ДЛЯ АНГЛОЯЗЫЧНЫХ ПУБЛИКАЦИЙ!: | A. Е. Калугин, К. A. Лыссенко, М. Е. Миняев, Д. М.Роитерштейн, Л. Н. Пунтус, Е. A. Вараксина, И. Е. Нифантъев |
| Подразделения (можно выбрать несколько, удерживая Ctrl): | 215 лаб. проблем субмикронной технологии |
| URI: | http://cplire.ru:8080/id/eprint/9074 |
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